Sharing a 1,700-acre estate with views of Mount Amiata in Tuscany's Val D'Orcia, this villa is pastoral perfection. Take the old stone path to a pool, chapel, soccer pitch, and dining pergola, and walk or bike a woodland path to tiny Sarteano. Inside, a red felt pool table stands out against antique stone walls and archways. The sulphur-rich waters of San Casciano dei Bagni are a 10-mile drive.